DataRow object doesn't have a Length method.
You can check every element or a specific element from that DataRow if it's null by looping through your DataRows or from your DataTable directly
Code:
If Dt.Rows.Count > 0 Then //Check the Rows count > 0 from DataTable
Drs = Dt.Select("memb___id=" + comboBox1.Text) // SELECT * FROM YOUR DATATABLE WHERE memb___id = comboBox1.Text (DataTable querying)
textBox2.Text = Drs["mail_addr"].ToString() // Not sure here but should work
End If
(I don't know VB.NET (Wannabe C# programming language) so it's hard to help you out, but I'll try)
DataRow are a single row from a DataTable. You need to specify what DataRow from DataTable you want to select first tho.
Suggestion and advice: Name your GUI objects according to their scope and usage because if you need some help in your code, no one wants to spend their time just trying to puzzle up every comboBox1, comboBox2, textBox1, textBox2, etc and we can see more easily what are you actually trying to do. Sometimes can be just a wrong object used from your code. (comboBox2 instead of comboBox1, etc...)
E.g.:
If you need a comboBox for Email: name it emailComboBox, etc.
If you need a textBox for entering a value for attributes: name it strengthTextBox, dexterityTextBox, etc.
Proper naming saves time!